Decentralized Autonomous Organizations (DAOs) are a new means of operating organizations and communities, utilizing blockchain technology and smart contracts to be free from central control. DAOs are reported to introduce transparency, democratic management, and self-management. However, as DAOs get more sophisticated, more issues such as inefficiency in the process of governing, vulnerability to security attacks, and failure to deal with large-scale participation occur. That is where Artificial Intelligence (AI) is increasingly becoming a game-changer.